Ti:Sapphire Laser Crystal

Titanium – Doped Sapphire

Titanium-doped sapphire is an optically pumped, solid-state laser material with an indefinitely long stability and useful life. It is the most widely used crystal for wavelength tunable lasers. And it is a leading material in the field of femtosecond pulse lasers. Ti:sapphire laser crystals combine the excellent thermal, physical and optical properties of sapphire with the broadest tunable range of any known material. Laser output can be can be generated over the entire spectrum from 650 nm to 1100 nm. Frequency doubling the output provides tunability across the blue-green region of the visible spectrum.

Laser designers are using Ti:sapphire to generate femtosecond pulses to create new industrial tools. A properly delivered femtosecond laser pulse interacts within the target leaving the surrounding area undisturbed. Newly developed femtosecond pulsed lasers micro-machine complex fine structures in glass, metal and other materials. Active waveguides can be written below the surface, integrating optical devices within the body of a substrate. Defects in photomasks can be repaired without disturbing neighbouring patterns. And it is now possible to achieve cellular resolution in vivo for medical diagnosis with femtosecond pulse lasers.

Roditi offers Ti:sapphire laser crystals made to order, matching your precise specifications. The crystals are available in sizes from 2mm to 30mm diameter or diagonal dimension and with path length from 2mm to over 100mm long. Crystals are prepared in several standard titanium concentrations, from 0.03% to 0.25%. They are regularly available with FOM > 150, FOM > 300 and by special order with FOM > 500. (Figure of Merit is measured as the ratio of α 820 nm : α 514 nm.)

A broad absorption pump band, peaking at 490 nm: High output efficiencies, gain of 10dB/cm is typical in crystals doped at 0.1%: Broadly tunable output: Excellent conditions for frequency doubling and femtosecond pulse generation make Ti:sapphire laser crystals an excellent choice for tunable and ultra fast pulse laser systems.

Applications
  • Femtosecond Pulse Laser Material
  • Tunable Output – 650 nm to 1100 nm
  • Excellent Output Efficiency
Optical and Laser Properties
Laser

Action

4

Level Laser

Refractive

Index

1.77

at 532 nm

Output

Wavelength

650

nm to 1100 nm

 

1.76 at 800 nm

Turnable

Absorption Band

400

nm to 600 nm

  1.75

at 1100 nm

Emission

Cross-section

Σ532nm

= 4.9 x 10-20

cm2

Chemical

Formula

Al2O3:Ti

  Σ490nm

= 6.4 x 10-20

cm2

 
Absorption Coefficient
Titanium

Wt%

α

at 532 nm

0.03% 0.60/cm

± 20%

0.05% 0.95/cm

± 20%

0.10% 1.50/cm

± 20%

0.15% 2.10/cm

± 20%

0.25% 4.10/cm

± 20%

Ti:sapphire Laser Rod Standard Fabrication Specifications
Feature Standard Special Order
Crystal

Orientation

A-Axis

within 5°

  (E-vector

parallel to C-Axis)

Diameter 4

mm to 12mm

Available
Diameter

Tolerance

+0.0

mm/- 0.05 mm

Available
Length

(plano/plano)

4

mm to 150 mm

Available

Length

Tolerance

± 0.75 mm ± 0.50 mm
Perpendicularity

of End Faces (plano/plano)

5

arc-minutes

2

arc-minutes

Parallelism

of End Faces (plano/plano)

10

arc-seconds

Flatness

0.1

wave maximum

0.10

wave maximum

(plano/plano) over

90% of aperture

over

full aperture

Surface

Finish at 5X

20-10

(scratch & dig)

10-5

(scratch & dig)

Barrel

Finish

400

grit

Polished

approx. 80-50

End

Face Bevel

0.075

mm to 0.12 mm at 45° angle

Chips No

chips allowed on end

face of rod; chip having

maximum length of 0.3

mm permitted to lie

in the area of bevel

and barrel surfaces.

End

Configurations

plano/plano,

plano/wedge, wedge/wedge

or Brewster cut. Plano

ends can be finished

flat, concave or convex

Coatings Standard

coating is BBAR with

R < 5.0% each face at

532 nm and R < 0.5%

each face, 650 nm to

850 nm.

Other

coatings available.

FOM,

α

820 mm : α

514 mm

   
0.03%

to 0.15% Ti

FOM

> 150, FOM > 300

FOM

500 and above

0.25%

Ti

FOM

> 75, FOM > 150

FOM

300 and above

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